RESUMO
Na exploração do petróleo, o uso de fluidos de perfuração é essencial para o equilíbrio da pressão entre as formações e o interior do poço, além de impedir o refluxo do reservatório de petróleo ao poço. Os fluidos também são responsáveis pela elevação dos cascalhos de perfuração à superfície. Entretanto, estes podem ser potenciais contaminantes do ambiente, uma vez que chegam à superfície impregnados de fluidos. O trabalho objetivou avaliar o pH e os teores de Na+, K+, Ca2+, Mg2+e Al3+em um Latossolo e um Planossolo submetidos a doses de fluido de perfuração, após sofrerem dois ensaios de lixiviação. Os resultados mostraram que a adição dos fluidos ao Planossolo e Latossolo nas concentrações de 4%, 8% e 16% (m/m) reduziu o alumínio tóxico a zero e promoveu aumento do pH do solo, Na+, K+e Ca2+em comparação ao controle.
In petroleum exploration, the use of drilling fluids is critical to the balance of pressure between the formations and the interior of the shaft, and preventing the backflow of oil from the reservoir to the oill well. Fluids are also responsible for raising the drill cuttings to the surface. However, these may potentially contaminate the environment once they arrive at the fluid-impregnated surface. This study aimed to check the pH and Na+, K+, Ca2+, Mg2+ and Al3+ in an Oxisol and Planosol subjected to doses of drilling fluid, after suffering two leaching tests. The results showed that the addition of fluids to Planosoland Oxisol at concentrations of 4%, 8% and 16% (w / w) reduced toxic aluminum to zero and promoted an increase of the soil pH, Na+, K+ and Ca2+ compared to control.
RESUMO
Two assays were designed to obtain information about the influence of redox potential variations on barium mobility and bioavailability in soil. One assay was undertaken in leaching columns, and the other was conducted in pots cultivated with rice (Oryza sativa) using soil samples collected from the surface of Gleysol in both assays. Three doses of barium (100,300 mg kg(-1) and 3000 mg kg(-1)-soil dry weight) and two redox potential values (oxidizing and reducing) were evaluated. During the incubation period, the redox potential (Eh) was monitored in columns and pots until values of -250 mV were reached. After the incubation period, geochemical partitioning was conducted on the barium using the European Communities Bureau of Reference (BCR) method. Rainfall of 200 mm d(-1) was simulated in the columns and in the planting of rice seedlings in the pots. The results of the geochemical partitioning demonstrated that the condition of reduction favors increased barium concentrations in the more labile chemical forms and decreased levels in the chemical forms related to oxides. The highest barium concentrations in leached extracts (3.36 mg L(-1)) were observed at the highest dose and condition of reduction at approximately five times above the drinking water standard. The high concentrations of barium in the soil did not affect plant dry matter production. The highest levels and accumulation of barium in roots, leaves, and grains of rice were found at the highest dose and condition of reduction. These results demonstrate that reduction leads to solubilization of barium sulfate, thereby favoring greater mobility and bioavailability of this element.
